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Manganese, tricarbonyl[(1,2,3,4,5-η⁵)-1-methyl-2,4-cyclopentadien-1-yl]-

• Formula: C₉H₇MnO₃
• Molecular Weight: 218.09
• CAS Registry Number: 12108-13-3
• Chemical Structure:
  This structure is also available as a 2d Mol file.
• Other Names: Manganese, tricarbonyl[(1,2,3,4,5-η)-1-methyl-2,4-cyclopentadien-1-yl]-; Manganese, tricarbonyl(methyl-π-cyclopentadienyl)-; π-(Methylcyclopentadienyl)manganese tricarbonyl; (Methylcyclopentadienyl)manganese tricarbonyl; (Methylcyclopentadienyl)tricarbonylmanganese; Methylcymantrene; Tricarbonyl(methyl-π-cyclopentadienyl)manganese; Tricarbonyl(methylcyclopentadienyl)manganese; Tricarbonyl(2-methylcyclopentadienyl)manganese; 2-(Methylcyclopentadienyl)manganesetricarbonyl; (η⁵-Methylcyclopentadienyl) manganese tricarbonyl-; (1-Methyl-2,4-cyclopentadien-1-yl)manganese tricarbonyl; Manganese methyl cyclopentadienyl tricarbonyl; Ak-33x; CI-2; Manganese, tricarbonyl methylcyclopentadienyl; Manganese, tricarbonyl(2-methylcyclopentadienyl)-; MMT; Antiknock-33; Combustion improver -2; Methylcyklopentadientrikarbonylmanganium; Manganese,tricarbonyl[1,2,3,4,5-η)-1-methyl-2,4-cyclopentadie-1-yl]-
• Gas phase ion energetics data
• Mass Spectrum
• References
• Notes / Error Report
• Switch to calorie-based units

Gas phase ion energetics data

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Data evaluated as indicated in comments:
HL - E.P. Hunter and S.G. Lias

Data compiled as indicated in comments:
LLK - S.G. Lias, R.D. Levin, and S.A. Kafafi

Ionization energy determinations

Appearance energy determinations

Mass Spectrum

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Data compiled by: NIST Mass Spec Data Center, S.E. Stein, director

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Additional Data

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Owner	NIST Mass Spectrometry Data Center
Origin	ETHYL CORPORATION, FERNDALE, MICHIGAN
Origin code	AST
Instrument	GEC
Instrument IE (eV)	70
Source temp. (C)	240
EPA MS number	25876

References

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Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413.  [all data]

Calabro and Lichtenberger, 1981
Calabro, D.C.; Lichtenberger, D.L., Valence ionizations of olefins coordinated to metals. Olefin dicarbonyl(η5-(methyl and pentamethyl)cyclopentadienyl)manganese complexes, J. Am. Chem. Soc., 1981, 103, 6846.  [all data]

Guimon, Pfister-Guillouzo, et al., 1979
Guimon, C.; Pfister-Guillouzo, G.; Mathey, F., Electronic structure of phosphacymantrene by photoelectron spectroscopy (He I, He II) and E.H.T. calculations, Nouv. J. Chim., 1979, 3, 725.  [all data]

Efraty, Huang, et al., 1975
Efraty, A.; Huang, M.H.A.; Weston, C.A., Mass spectra of organometallic compounds. V. Electron-impact study of the cyclopentadienylmanganese thiocarbonyl and carbonyl complexes RC₅H₄Mn(CO)₂CX [R=H, CH₃; X = S, O], Inorg. Chem., 1975, 14, 2796.  [all data]

Calabro, Hubbard, et al., 1981
Calabro, D.C.; Hubbard, J.L.; Blevins, C.H., II; Campbell, A.C.; Lichtenberger, D.L., The effects of methyl group substitution on metal-coordinated cyclopentadienyl rings. The core and valence ionizations of methylated tricarbonyl(η5-cyclopentadienyl)metal complexes, J. Am. Chem. Soc., 1981, 103, 6839.  [all data]

Notes / Error Report

Go To: Top, Gas phase ion energetics data, Mass Spectrum, References

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