½s¸¹: HSN-1251
¤é´Á: DATE-890505
³ü. SUBSTANCE IDENTIFICATION <<ª«½è½T»{>>
(A) NAME:¦WºÙ: ¤²¸¤ÆÁC (Phosphorus Sulfide)
(B) SY:§O¦W
(1) DIPHOSPHORUS PENTASULFIDE **PEER REVIEWED**
(2) PENTASULFURE DE PHOSPHORE [FRENCH] **QC REVIEWED**
(3) PHOSPHORIC SULFIDE **PEER REVIEWED**
(4) PHOSPHORUS PENTASULFIDE (P4S10) **PEER REVIEWED**
(5) PHOSPHORUS PERSULFIDE **PEER REVIEWED**
(6) PHOSPHORUS SULFIDE [P2S5] **PEER REVIEWED**
(7) SIRNIK FOSFORECNY [CZECH] **QC REVIEWED**
(8) TETRAPHOSPHORUS DECASULFIDE **PEER REVIEWED**
(9) THIOPHOSPHORIC ANHYDRIDE **PEER REVIEWED**
(10) SULFUR PHOSPHIDE **QC REVIEWED**
(C) MF:¤À¤l¦¡: P2-S5
(D) RN: CAS ¤Æ¾Çµù¥U¸¹½X: 1314-80-3
(E) SHPN:¥@¬É½Ã¥Í²Õ´¹B¿éª««~¦W/½s¸¹: UN 1340; Phosphorus pentasulfide
¶L. MANUFACTURING/USE INFORMATION <<»s³y¤Î¨Ï¥Î>>
(A) MMFG:»s³y¤èªk
º²¤ÆºA¥Õ (¶À) ÁC¥[¨ìº²¤ÆºA²¸¤¤,
¦A¸g¤G²¸¤ÆºÒ²M¬~¥H°£¥h¤Ö¶q¤G¤T²¸
¤ÆÁC (phosphorus sesquisulfide) ¤Î´åÂ÷²¸ªº¯Â¤Æ³B²z¦Ó±o.
(B) IMP:¤£¯Âª«
(C) MFS:»s³yªÌ
(1) MONSANTO CO, MONSANTO INDUST CHEMS CO, ANNISTON, AL,
SAUGET, IL[SRI ] **QClREVIEWED**
(2) OCCIDENTAL PETROLEUM CORP, HOOKER CHEM CORP, SUBSID,
HOOKER CHEMS AND PLASTICS CORP, SUBSID, ELECTROCHEMICAL
AND SPECIALTY CHEMS DIV, COLUMBUS, MI, NIAGARA FALLS, NY
[SRI ] **QC REVIEWED**
(3) STAUFFER CHEM CO, INDUST CHEM DIV, MT PLEASANT, TN,
SPECIALTY CHEM DIV, MORRISVILLE, PA, NASHVILLE, TN [SRI ]
**QC REVIEWED**
(4) FMC CORP, (HQ), 2000 MARKET ST, PHILADELPHIA, PA 19103,
(215)299-60000; LAWRENCE, KS [CHEMICAL PRODUCTS SYNOPSIS:
PHOSPHORUS PENTASULFIDE, 1985] **QC REVIEWED**
(D) USE:¥Dn¥Î³~
(1) ¦w¥þ¤õ®ã¤ÎÂI¤õ¤Æ¦Xª«ªº»s³y¤Î±N²¸²V¤J¦³¾÷¤Æ¦Xª«¤¤.
(2) ¼í·Æªo²K¥[ª«ªº¤Æ¾Ç¤¤¶¡²£ª«; º}¯B¾¯ (flotation agent) ¦¨¤À; ¤U¦C
±þÂξ¯ªº¤Æ¾Ç¤¤¶¡²£ª«: dimethoate, imidan, °¨©ÔªQ (malathion),
supracide, abate, famphur, ªâ±þªQ (fenthion), ¤Î¥Ò°ò¤Ú©ÔªQ (methyl
parathion); monitor, ronnel, sumithion, metasystox-R,counter, delnav,
di-syston, torak, ¤Î ethion thimet, guthion,trithion, zolone, co-ral, cytrolane,
dasanit, ciazinon, ¤Îdursban mobilawn, ¤Ú©ÔªQ (parathion), systox, ¤Î
aspon; °£¯ó¾¯, bensulfide.
(E)<LMFI:¥»¦a»s³y¤Î¶i¤f¼t°Ó> (Local Manufacture & Importer)
(1) NAAD:¼t°Ó¦WºÙ¤Î¦í§}
(2) PROD:²£¶q(¶i¤f¶q)
(a) 1972 ¦~ 5.55 x 10 ¤½§J.
(b) 1975 ¦~ 5.58 x 10 ¤½§J.
(c) 1984 ¦~ 6.74 x 10 ¤½§J.
°Ñ. CHEMICAL & PHYSICAL PROPERTIES <<ª«²z¤Î¤Æ¾Ç©Ê½è>>
(A) COFO:ÃC¦â/©Êª¬: ¦Ç¶À¦â´¹Åé.
(B) ODOR:¨ý¹D: µL¨ý©Î»G±Ñ³J¨ý.
(C) TAST:À|¨ý
(D) BP:ªmÂI: 513-515¢J
(E) MP:º²ÂI: 286-290¢J
(F) MW:¤À¤l¶q: 222.29
(G) CORR:»G»k©Ê
(H) CTP:Á{¬É·Å«×¤ÎÀ£¤O
(I) DEN:±K«×¤Î¤ñ«: 2.09
(J) DSC:¸ÑÂ÷±`¼Æ
(K) OWPC:¨¯¾J»P¤ô¤§¤À°t«Y¼Æ
(L) PH:pHÈ
(M) SOL:·»¸Ñ«×: ¤£·»©ó§N¤ô¤¤; ¥i·»©ó¤G²¸¤ÆºÒ¤¤: 0.22 g / 100 cc.
(N) SPEC:¥úÃЯS©Ê
(O) VAP:»]®ðÀ£: 300¢J ®É 1 mm-Hg.
(P) VISC:ÂH¸Y«×
(Q) OCPP:¨ä¥¦©Ê½è: ¤²¸¤ÆÁC©M¤ô±µÄ²·|¤À¸Ñ²£¥ÍÁC»Ä, ¤G®ñ¤Æ²¸¤Î²¸¤Æ²B.
¸v. SAFETY & HANDLING <<¦w¥þ©Ê¤Î³B²z>>
(A) DOT:·N¥~¨a®`ºò«æ³B²z¤è°w
(1) ¤õ¨a©ÎÃz¬µ:
(a) ¦³Àã®ð®É, ¥i¯à·|³QÂI¿U.
(b) ±µÄ²¨ì¤ô®É·|²£¥Í¥i¿U©Ê®ðÅé.
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(2) °·±dªº¦M®`:
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(3) ºò«æ³B²z:
(a) ²¨´²«D¥²n¤Hû, ¹jÂ÷¨a°Ï°ì¤Îªýµ´¨aÅܤJ¤f.
(b) ¯¸¥ß¦b¤W·³B, ÁקK¶i¤J§C³B.
(c) ¶i¤J¨a°Ï®É»Ý°t¸ü¦³¥¿À£ªº©I§l¸Ë¸m¤Î¬ïµÛ¯S®íªº¨¾Å@¦ç.
(d) ¦pªG¦Ã¬V¨ì¤ô·½, ¥ß§Y³qª¾¦³Ãö·í§½. Àô«O¸p¬rºÞ³B¹q¸Ü: (02)311-6067.
(4) °_¤õ®É: ¤£¥i¨Ï¥Î¤ô©Îªwªj¨Ó·À¤õ.
(a) ¤p¤õ®É: ¥i¥Î°®¦¡¤Æ¾Ç¸Õ¾¯¡NĬ¥´¦Ç©Î¥Û¦Ç.
(b) ¤j¤õ®É: ºMÂ÷¤õ³õ, Åý¤õ¦Û¦æ¿U¿N.
(c) ¦b¤£¦M¤Î¤Hû¦w¥þ±¡ªp¤U, ±N®e¾¹¦Û¤õ³õ¤¤²¾¨«.
(5) Âq¥X©Î¥~·¸:
(a) ¤@¯ë³B²z:
(¢¹) Ãö±¼¿U¿Nªº¨Ó·½.
(¢º) ¤£¥i¦b¦M®`°Ï©â·Ï©Î¿U¿N¥ô¦óªF¦è.
(¢») ¤£¥i¸IIJ¼âÅxª«½è.
(¢¼) ¤£¥i¥Î¤ô¨Ó¼QÅx¦¹·¸¥Xª«.
(¢½) ®e¾¹¤¤¤£¥i§t¤ô.
(b) ¤Ö¶q°®Àꤲ¸¤ÆÁC¼âÅx®É:
¥Î°®²bªºÃê¤l±N¨ä©ñ¸m¨ì°®²b¥B°®Àꪺ®e¾¹¤º, ¨Ã¥B¥[»\, µM«á¦A
±N¦¹®e¾¹²¾¨«.
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(¢¹) ¿v³ö, «Ý¥H«á³B²z.
(¢º) ±N¼»¥Xªº¯»¥½¥Î¶ì½¦¯È»\°_¨Ó, ¾¨¶qÁY¤p´²§G½d³ò. ²M°£®É¥²
¶·¦b±M®a«ü¾É¤U, ¤è¥i¶i¦æ.
(6) «æ±Ï±¹¬I:
(a) ±N¶ËªÌ²¾¦ÜªÅ®ð·sÂA³B, Ápµ¸«æ±ÏÂåÀø±Ï§U.
(b) ¹ï°±¤î©I§lªº¶ËªÌ, ¬I¥H¤H¤u©I§l; ¹ï©ó©I§l§xÃøªº¶ËªÌ, ¬I¥H®ñ®ð¨ó§U.
(c) ¦pªG²´·ú¤£¤p¤ß±µÄ²¨ì¤²¸¤ÆÁC, À³¥ß§Y¥Î¤j¶q²M¤ô¨R¬~ 15
¤ÀÄÁ¥H¤W.
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(d) ²æ°£¨Ã¹jÂ÷¨ü¦Ã¬Vªº¦çªA¤Î¾c¤l.
(e) «O«ù¶ËªÌªº¥ÀR¤Îºû«ù¥¿±`ªºÅé·Å.
(B)<FLAM:¥i¿U©Ê>
(1) FPOT:¿U¿N¼ç¦b©Ê
(a) ¤²¸¤ÆÁC¿U¿N½wºC, ¦ý¥i¸g¥Ñ¤p¤õ¨³³tÂI¿U, ¼éÀã®É¥i¦Û°Ê¥[¼öÂI¿U.
(b) ¥i¸g¥Ñ¤õªá¿iÀ¿©ÎÀR¹q©ñ¥X¦ÓÂI¿U.
(2) NFPA:¦M®`µ¥¯Å
(a) ¥i¿U©Ê¯Å¼Æ: 1
1 ªí¥Ü¦¹ª«½è¦bÂI¿U«en¥ý¥[¼ö, ¤ô¦pªG¬y¨ì¦¹²GÅé¤U¼h¨ÃÂàÅܦ¨
»]®ð®É¥i²£¥Íªwªj,¬G·í¤ôÃú·À¤õ®É¦]ªwªj¼hªº²£¥Í¦Ó¹F¨ì·À¤õªº
®ÄªG.
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2 ªí¥Ü¦¹ª«½è¥»½è¤W¤£Ã©w, ·|§Ö³tªº¶i¦æ¼@¯Pªº¤Æ¾ÇÅܤÆ, ¦ý¤£
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¦³Ãz¬µ¤Oªº²V¦Xª«.
(c) °·±d¦M®`¯Å¼Æ: 2
2 ªí¥Ü¦¹ª«½è¹ï°·±d¦³®`, ¦ý¦b¬ïÀ¹¦Û°t®ð²~¤§©I§l¾¹«á¥i¶i¤J¦Ã¬V°Ï.
(d) °·±d¦M®`¯Å¼Æ: 3
3 ªí¥Ü¦¹ª«½è¹ï°·±d¦³·¥¤j¦M®`©Ê, ¦ý¦b·¥¤p¤ß¨¾½d¤U¤´¥i¶i¤J¼É
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®M , ªø¹u¤Î»L¡NÁu¤Î¸y³¡ªº§ô±a, ¤£¥i¦³¥ô¦ó¥Ö½§ªí±¼ÉÅS¥X¨Ó.
(3) FLMT:¥i¿U½d³ò
(4) FLPT:°{¤õÂI
(5) AUTO:¦Û¿UÂI
260-290¢J(500-554¢K) (¤²¸¤ÆÁC·L²É); ¬ù 275¢J(527¢K) (¤²¸¤ÆÁC²GÅé).
(C)<FIRE:·À¤õ¸ê®Æ>
(1) FIRP:·À¤õ¤èªk
¥Î¤G®ñ¤ÆºÒ·À¤õ; ¥Î¤ô·À¤õ¦³®Ä, ¦ý¤ô·|©M¥¼¿U¿Nªº¤²¸¤ÆÁC¤ÏÀ³
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µÛ¤õ, ¹ï¤²¸¤ÆÁCµÛ¤õ¤]¦³®Ä).
(2) TOXC:¿U¿N«á¬r©Ê²£ª«
¤²¸¤ÆÁCµÛ¤õ·|²£¥Í¦³¬r©Ê¤Î¨ë¿E©Êªº®ðÅé,
¿U¿N²£ª«¥]§t¤G®ñ¤Æ²¸
¤Î¤²¸¤ÆÁC, ¦¹¤GªÌ¬Ò¦³¨ë¿E©Ê, ¬r©Ê¤Î»G»k©Ê.
(3) OFHZ:¨ä¥¦·À¤õ¦M®`©Ê
(4) EXPL:Ãz¬µ¼ç¦b©Ê¤Î½d³ò
(a) ¤²¸¤ÆÁC©TÅé¸g¦Ûµo©Ê¤Æ¾Ç§@¥Î¦³²£¥Í¤¤µ¥µ{«×ªºÃz¬µ.
(b) ¤õ³õ¤¤¤²¸¤ÆÁCªº¸Ë¸ü®e¾¹¥i¯à·|Ãz¬µ.
(D)<HAZR:¦M®`¤ÏÀ³>
(1) REAC:¤ÏÀ³©Ê¤Î¤£¥i¬Û®e©Ê
¤²¸¤ÆÁC©M¤ô©Î»Ä±µÄ²·|©ñ¥X¦³¬r©Ê¤Î¥i¿U©Ê²¸¤Æ²B.
(2) DCMP:¤À¸Ñ©Ê
¤²¸¤ÆÁC¥[¼ö¤À¸Ñ·|©ñ¥X°ª¬r©Ê®ñ¤Æ²¸ (SOx) ¤Î®ñ¤ÆÁC (POx) ·ÏÃú.
(3) POLY:»E¦X©Ê
(4) OHAZ:¨ä¥¦¦M®`¤ÏÀ³
(E)<WRNP:¥Üĵ©Ê½è>
(1) ODRT:¶å¨ý»ÖÈ
(2) SERI:¥Ö½§/²´·ú/©I§l¹D¤§¨ë¿E©Ê
(F)<PRVN:¨¾Å@³B¸m>
(1) EQUP:¨¾Å@³]³Æ
¤Æ¾Ç¦w¥þÅ@¥ØÃè; ¶ì½¦±¸n; ¦Û³ÆªÅ®ð©ÎªÅ®ð½u¸ô«¬¦¡ (air-line) ªº©I§l¾¹.
(2) OPRM:¨ä¥¦¨¾Å@¤èªk
(a) ¤²¸¤ÆÁC¤u¤H¤£¥i°tÀ¹Áô§Î²´Ãè.
(b) °ò¥»³q·¤è¦¡¬O§½³¡±Æ®ð³q·ªk¤Îµ}ÄÀªk©Î¤@¯ë³q·ªk.
(G) SSL:¦w©w©Ê/¥b¥Í´Á
¤²¸¤ÆÁC¥i³Q¼éÀ㪺ªÅ®ð¤À¸Ñ±¼.
(H) SHIP:¸Ë¹B(¤èªk¤Î³W©w)
®e¾¹: ÅÖºû©Î¤£úM¿û¶ê±í; ·h¹B±M¥ÎÂd (tote bins).
(I) STRG:Àx¦sª¬ªp
¨¾½dª«²z©Ê¸I¼²¤Î¤ô»]®ð«Iŧ, »·Â÷®ñ¤Æ¾¯.
(J) CLUP:²M°£¤èªk
(1) ¨Ï¥~¬ª°Ï«O«ù³q·¨}¦nª¬ªp.
(2) ¤Ö¶q¥~¬ªµo¥Í®É , ±N¥~¬ªª«±½¨ì¯È©Î¨ä¥¦¾A·íª«½è¤W,
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®ð²M¼ä¸Ë¸mªº¿U¿N«Ç¿N±¼.
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(K) DISP:³B¸m¤èªk
(1) ±N¤²¸¤ÆÁC¥Î¯È©Î¨ä¥¦¥i¿Uª«½è¥]¸Ë°_¨Ó,
¦A©ñ¨ì¦³¨}¦n¼o®ð²M¼ä
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(2) ±N¤²¸¤ÆÁC·»¸Ñ¦b¥i¿U·»¾¯ (¦p°sºë) ¤º,
¦A©ñ¨ì¦³¨}¦n¼o®ð²M¼ä¸Ë
¸mªº¿U¿N«Ç¿N·´.
¥î. TOXICITY/BIOMEDICAL EFFECTS <<¬r©Ê/¥Í²z¾Ç®ÄÀ³>>
(A) TOXS:¬r©ÊºKn
(B) TXHR:¬r©Ê¦M®`µ¥¯Å
«æ©Ê§½³¡: ¨ë¿Eª« 3; «æ©Ê¥þ¨: ¥ÑªÅ®ð§l¤J 3; ¤fªAÄá¤J 3, 3 ªí¥Ü¦³
°ª«×¬r©Ê: ·¥µu®É¶¡¼ÉÅS¦b¤Ö¶q¤²¸¤ÆÁC¤U¥i¯àP¦º©Î³y¦¨¥Ã¤[©Ê
¶Ë®`; ºC©Ê§½³¡: ¨ë¿Eª« 2, 2 ªí¥Ü¦³¤¤µ¥µ{«×¬r©Ê: ¥i¤Þ°_¤£¥i°f¤Î
¥i°f©ÊªºÅܤÆ, ¦ý¤£·|ÄY«¨ìP¦º©Î³y¦¨¥Ã¤[©Ê¶Ë®`.
(C) PPOT:¤¤¬r¼ç¦b©Ê
(D) ANTR:¸Ñ¬r»Pºò«æ³B²z
(E) MEDS:ÂåÅ@ºÊ·þ
(F) HTOX:¤HÃþ¬r©Ê
°Ñ¦Ò²¸¤Æ²B³¡¤À, ¯gª¬¾Ç: A, §C¨ì¤¤µ¥µ{«×»]®ð¿@«×:
(1) ¨ë¿E§@¥Î: ²´·ú: ¯kµhªºµ²½¤ª¢, ¬È¥ú,
²´²\¤Àªc¼W¥[¤Î¨¤½¤Åܬ°¸û
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·|¾É
P¬õ´³¤Î¯kµh.
(2) G¸z¹D§@¥Î: ³è²G¼W¥[, äú¤ß, ¹Ã¦R, ¸¡Âm.
(3) ¤¤¼Ï¯«¸g§@¥Î: ²´ªá, ÀYµh, ÀY©ü, °·§Ñ, ·NÃѼҽk¤Î·NÃѳॢ.
(4) ²V¦X§@¥Î: ©I§l¥[³t, ¤ß±ª, ¤ß¸õ¥[³t, ¤ß«ß¤£¾ã, ¬y¦½¼W¥[,
µê®z¤Î
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(G) NTOX:«D¤HÃþ¬r©Ê
(H)<TOXV:¬r©ÊÈ>
(1) HTXV:¤HÃþ¬r©Ê¼Æ¾Ú
(2) NTXV:«D¤HÃþ¬r©Ê¼Æ¾Ú
(3) ETXV:¥ÍºA¬r©Ê¼Æ¾Ú
(4) MINF:³Ì§CP¦º¾¯¶q
(5) POPL:°ª¦MÀI¸s
(6) IARC:¥@¬É½Ã¥Í²Õ´¹ïPÀù©Êªº§PÂ_
(I)<PHMK:ÃĪ«°Ê¤O¾Ç>
(1) ADE:§l¦¬/¤À§G/±Æªn
(2) METB:¥NÁ¤Ψ䲣ª«
(3) BHL:¥Íª«¥b¥Í´Á
(4) ACTN:§@¥Î¾÷¨î
(5) INTC:»PÃĪ«¤§¥æ¤¬§@¥Î
³°. PHARMACOLOGY <<ÃIJz¾Ç>>
(A) BION:¥ÍÅé»Ý¨D
(B) THER:ªvÀø¥Î³~
(C) WARN:ÃĪ«Äµ§Ù
(D) IDIO:ÃĪ«¯S²§©Ê
(E) TOLR:ÃĪ«§Ô¨ü©Ê
(F) MXDD:¥ÎÃij̤j¾¯¶q
¬m. ENVIRONMENTAL FATE/EXPOSURE POTENTIAL <<Àô¹Ò¬y§G>>
(A)<POLL:¦Ã¬V·½>
(1) NATS:¦ÛµM¦Ã¬V·½
(2) ARTS:¤H¬°¦Ã¬V·½
(B) FATE:Àô¹Ò¬y§G
(C)<ENVT:Àô¹ÒÂà´«©Ê>
(1) BIOD:¥Íª«¤À¸Ñ©Ê
(2) ABIO:«D¥Íª«¤À¸Ñ©Ê
(D)<ENTP:Àô¹ÒÂಾ©Ê>
(1) BIOC:¥Íª«¿@ÁY
(2) KOC:¤gÄ[§l¦¬¤Î²¾°Ê
(3) VWS:¦Û ¤ô/¤gÄ[ ´§µo©Ê
(E)<ENVC:Àô¹Ò¿@«×>
(1) WATC:¤ôÅé¿@«×
(2) EFFL:©ñ¬y¤ô¿@«×
(3) SEDS:©³ªd/¤gÄ[¿@«×
(4) ATMC:ªÅ®ð¿@«×
(5) FOOD:¹«~´úÈ
(6) PLNT:´Óª«Åé´úÈ
(7) FISH:³½Ãþ/®ü²£´úÈ
(8) ANML:°Êª«Åé´úÈ
(9) MILK:¤û¥¤´úÈ
(10) OEVC:¨ä¥¦Àô¹Ò´úÈ
(F)<HUEX:¤HÃþ¼ÉÅS>
(1) RTEX:¥i¯à¼ÉÅS³~®|
(2) AVDI:¨C¤é¥§¡Äá¤J¶q
(3) PBEX:¥i¯à¼ÉÅSª¬ªp
(4) BODY:¤HÅét²ü¶q
®Ã. EXPOSURE STANDARDS & REGULATIONS <<¼ÉÅS¼Ð·Ç¤Î³W©w>>
(A) IDLH:¥ß§Y¦M®`¶q(¿@«×)750 mg/¥ß¤è¤½¤Ø.
(B) ADI:¨C¤é¥i±µ¨üÄá¤J¶q
(C) ATOL:®e³\¶q
(D)<OPL:¾·~¤W¤¹³\¶q>
(1) OSHA:¾·~¦w¥þ»P°·±dºÞ²z§½³W©w
(2) NREC:°ê»Ú¾·~¦w¥þ¤Î°·±d¨ó·|n¨D
(3) TLV:»ÖÈ
³æ¦ì®É¶¡¥§¡»ÖÈ 1 mg/¥ß¤è¤½¤Ø; µu®É¶¡¼ÉÅSÈ 3 mg/¥ß¤è¤½¤Ø
(1987-1988 ¦~).
(4) OOPL:¨ä¥¦Â¾·~©Ê¤¹³\¶q
(E)<OREG:¨ä¥¦¼Ð·Ç»P³W©w>
(1) WSTD:¤ô½è¼Ð·Ç
(2) ASTD:ªÅ®ð¼Ð·Ç
(3) SSTD:¤gÄ[¼Ð·Ç
(F) TSCA:¬rª«ºÞ¨îªk
(G) RCRA:¸ê·½«O¦s¦^¦¬ªk
(H) FIFR:Áp¨¹±þÂÎ,§ÜÅð,·À¹«¥ÎÃĪk
(I) FDA:¹«~ÃĪ«ºÞ²zªk
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